Complex permittivity‐dependent plasma confinement‐assisted growth of asymmetric vertical graphene nanofiber membrane for high‐performance Li‐S full cells
Yongshang Zhang,
Zhiheng Wu,
Shaobin Wang,
Neng Li,
S. Ravi P. Silva,
Guosheng Shao,
Peng Zhang
Affiliations
Yongshang Zhang
State Center for International Cooperation on Designer Low‐Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering Zhengzhou University Zhengzhou China
Zhiheng Wu
State Center for International Cooperation on Designer Low‐Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering Zhengzhou University Zhengzhou China
Shaobin Wang
School of Chemical Engineering and Advanced Materials University of Adelaide Adelaide South Australia Australia
Neng Li
State Key Laboratory of Silicate Materials for Architecture Wuhan University of Technology Wuhan China
S. Ravi P. Silva
State Center for International Cooperation on Designer Low‐Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering Zhengzhou University Zhengzhou China
Guosheng Shao
State Center for International Cooperation on Designer Low‐Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering Zhengzhou University Zhengzhou China
Peng Zhang
State Center for International Cooperation on Designer Low‐Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering Zhengzhou University Zhengzhou China
Abstract Vertical graphene (VG), possessing superior chemical, physical, and structural peculiarities, holds great promise as a building block for constructing a high‐energy density lithium‐sulfur (Li‐S) battery. Therefore, it is desirable to develop a new VG growth technique with a novel structure to enable wide applications. Herein, we devise a novel complex permittivity‐dependent plasma confinement‐assisted VG growth technique, via asymmetric growing a VG layer on one side of N‐doped carbon nanofibers for the first time, using a unique lab‐built high flux plasma‐enhanced chemical vapor deposition system, as a bifunctional nanofiber membrane to construct Li‐S batteries with low negative/positive (N/P) and electrolyte/sulfur (E/S) ratios. The unique nanofiber membrane could simultaneously protect the cathode and anode, enabling an excellent electrochemical performance with low N/P and E/S ratios in Li‐S batteries. Such a full cell delivers high gravimetric energy density and volumetric energy density of 340 Wh kg−1 and 547 Wh L−1, respectively, at low N/P (2:1) and E/S (4:1) ratios. Furthermore, a pouch cell achieves a high areal capacity of 7.1 mAh cm−2 at a sulfur loading of 6 mg cm−2. This work put forward a novel pathway for the design of high‐energy density Li‐S batteries.
