Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates

Kairui Liu; Guangjin Hou; Jingbo Mao; Zhanwei Xu; Peifang Yan; Huixiang Li; Xinwen Guo; Shi Bai; Z. Conrad Zhang

doi:10.1038/s41467-019-08804-y

Nature Communications (Mar 2019)

Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates

Kairui Liu,
Guangjin Hou,
Jingbo Mao,
Zhanwei Xu,
Peifang Yan,
Huixiang Li,
Xinwen Guo,
Shi Bai,
Z. Conrad Zhang

Affiliations

Kairui Liu: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Guangjin Hou: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Jingbo Mao: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Zhanwei Xu: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Peifang Yan: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Huixiang Li: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Xinwen Guo: State Key Laboratory of Fine Chemicals, PSU-DUT Joint Centre for Energy Research, School of Chemical Engineering, Dalian University of Technology
Shi Bai: Department of Chemistry and Biochemistry, University of Delaware
Z. Conrad Zhang: State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences

DOI: https://doi.org/10.1038/s41467-019-08804-y
Journal volume & issue: Vol. 10, no. 1
pp. 1 – 8

Abstract

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Synthesis of discrete reduced metal atoms weakly coordinated and stabilized in liquid media remains challenging. Here, the authors report the genesis of mononuclear electron deficient Pt1(0) in polydimethylsiloxane-polyethylene glycol aggregates, and its ultrahigh activity in olefin hydrosilylation with excellent terminal adducts selectivity.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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