Improved simultaneous adsorption of Cu(II) and Cr(VI) of organic modified metakaolin-based geopolymer

Abstract

In this paper, a metakaolin-based mesoporous geopolymer (GP-CTAB) was used as adsorbent for Cu(II) and Cr(VI) through a novel and simple synthetic route using cetyltrimethylammonium bromide (CTAB) as an organic modifier. The application of GP-CTAB for the simultaneous removal of metal anions and cations in aqueous solution was studied for the first time. The results of X-ray diffraction (XRD) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, Brunauer, Emmett and Teller (BET), and Barrett, Joyner, and Halenda (BJH) methods indicate that GP-CTAB is still geopolymer even in the presence of quaternary ammonium salt cations. The material was tested to simultaneously adsorb Cu(II) and Cr(VI) from an aqueous solution. The results show that GP-CTAB can adsorb anions simultaneously without sacrificing the adsorption properties of heavy metal cations, which is superior to conventional geopolymers. The maximum theoretical adsorption capacity of GP-CTAB for Cu(II) and Cr(VI) was 108.2 mg/g and 95.3 mg/g in the binary system, respectively. It was also found that the presence of Cu(II) in the solution promoted the adsorption of Cr(VI). Given this characteristic of GP-CTAB, it has shown great application prospects in the prevention and control of heavy metal pollution. Keywords: Geopolymer, Co-sorption, CTAB, Copper ion, Hexavalent chromium ion