Acta Crystallographica Section E (Oct 2008)
Tetraaquabis(2-sulfamoylbenzoato)manganese(II)
Abstract
In the title compound, [Mn(C7H6NO4S)2(H2O)4], the Mn atom, lying on an inversion center, exhibits a distorted octahedral coordination by six O atoms, two from carboxylate groups and four from water molecules. The SO2NH2 group is involved in a three dimensional polymeric hydrogen bonding network along with the water molecules. π-Stacking interactions parallel to the c axis lead to a separation of 4.0050 (12) Å between the centroids of the benzene rings.