Beilstein Journal of Organic Chemistry (Aug 2024)
From perfluoroalkyl aryl sulfoxides to ortho thioethers
Abstract
Access to original ortho thioether derivatives was achieved through a [3,3]-rearrangement in a one-pot two-step protocol. Several aryl-SCF3 compounds are reported by variation of the nitrile or of the trifluoroalkyl sulfoxide starting material. The variation of the perfluoroalkyl chain was also possible.
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