Beilstein Journal of Organic Chemistry (Aug 2024)

From perfluoroalkyl aryl sulfoxides to ortho thioethers

  • Yang Li,
  • Guillaume Dagousset,
  • Emmanuel Magnier,
  • Bruce Pégot

DOI
https://doi.org/10.3762/bjoc.20.181
Journal volume & issue
Vol. 20, no. 1
pp. 2108 – 2113

Abstract

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Access to original ortho thioether derivatives was achieved through a [3,3]-rearrangement in a one-pot two-step protocol. Several aryl-SCF3 compounds are reported by variation of the nitrile or of the trifluoroalkyl sulfoxide starting material. The variation of the perfluoroalkyl chain was also possible.

Keywords