Biodiesel Synthesis from Coconut Oil Using the Ash of <i>Citrus limetta</i> Peels as a Renewable Heterogeneous Catalyst

Abstract

The synthesis of biodiesel can be achieved using either homogeneous or heterogeneous catalysts. Given the non-renewable nature of homogeneous catalysts, heterogeneous catalysts are increasingly preferred for biodiesel production. Agricultural wastes serve as a viable source for these heterogeneous catalysts, contributing to environmental sustainability. This study introduces a novel, eco-friendly, cost-effective, and efficient heterogeneous catalyst that was developed and derived from Citrus limetta peels for biodiesel production. The catalyst was thoroughly characterized using Fourier-transform infrared spectroscopy (FTIR), X-ray diffractograms (XRD), Field Emission Scanning electron microscopy (FESEM), and energy-dispersive X-ray (EDX). Coconut oil, a rich and renewable resource, was used as the feedstock for the biodiesel synthesis. The conversion process was confirmed by 1H NMR, IR spectra, mass spectra, and 13C NMR of the biodiesel. The developed method using the Citrus limetta peel-derived catalyst demonstrated a 100% yield. The results show the optimum conditions for biodiesel synthesis are 1 w/v (for the catalytical dose), with a 6:1 methanol/oil ratio at 60 °C for 3 h. The synthesized biodiesel exhibited a high cetane value of 54, contributing to improved ignition and reduced engine noise. Its sulfur-free composition, boiling point of 294 °C, high viscosity of 2.5 mm2/s, acid value of 0.09 mgKOH/g, and flash point of 142 °C enhance its environmental profile. The catalyst can be used for up to five cycles, underscoring its potential as a cost-effective and sustainable approach for biodiesel production.

Keywords

• biodiesel
• calcined
• sweet lime peels
• transesterification
• heterogeneous acid catalyst
• waste biomass