Nature Communications (Jul 2017)

Highly-conducting molecular circuits based on antiaromaticity

  • Shintaro Fujii,
  • Santiago Marqués-González,
  • Ji-Young Shin,
  • Hiroshi Shinokubo,
  • Takuya Masuda,
  • Tomoaki Nishino,
  • Narendra P. Arasu,
  • Héctor Vázquez,
  • Manabu Kiguchi

DOI
https://doi.org/10.1038/ncomms15984
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 8

Abstract

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Antiaromatic molecules are predicted to have unusual charge transport properties, but are notoriously unstable and reactive. Here, the authors successfully fabricate an antiaromatic molecular circuit, based on a macrocyclic complex, displaying much higher conductance than its aromatic counterpart.