High Temperature Materials and Processes (Feb 2019)

The effect of MgTiO3Adding on Inclusion Characteristics

  • Chen Xu,
  • Mingya Zhang,
  • Jianli Li,
  • Songlin Ran,
  • Mengwei Shan,
  • Qiang Yue,
  • Hui Kong

DOI
https://doi.org/10.1515/htmp-2019-0004
Journal volume & issue
Vol. 38, no. 2019
pp. 576 – 581

Abstract

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MgTiO3 powder was directly added into molten steel at 1873K, and its effect on inclusion characteristics was studied by a scanning electron microscope and an energy dispersive spectrometer. Thermodynamic calculation indicates that MgTiO3 is unstable in molten steel and may decompose into [Ti], [O] and MgO. However, only Ti-bearing inclusions were observed in the treated sample, and Mg-bearing inclusions were absent. This can be explained by the features of wettability and stability for MgO. Compared with a Non-treated sample, both oxide and coarse MnS in treated sample were refined. For the oxide, this originates from the formation of Ti-bearing inclusion. For coarse MnS, this may be due to the fact that Ti can aggravate S segregation. Besides, this aggravation makes coarse MnS less globular. After etching, it was found that in the treated sample, Ti-bearing inclusion can induce the nucleation of intragranular acicular ferrites. This appearance was totally different from that of Non-treated sample, and indicates the effectiveness of external adding method in oxide metallurgy.

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