Data on FTIR, photo-DSC and dynamic DSC of triethylene glycol dimethacrylate and N-vinylpyrrolidone copolymerization in the presence of ionic liquids
Sergey Nechausov,
Anna Ivanchenko,
Oleg Morozov,
Aslan Miriyev,
Indrek Must,
Oskars Platnieks,
Maksims Jurinovs,
Sergejs Gaidukovs,
Alvo Aabloo,
Mirko Kovač,
Boris Bulgakov
Affiliations
Sergey Nechausov
Department of Chemistry, Lomonosov Moscow State University, 119991, Leniskie gory 1-3, Moscow, Russia; Corresponding author.
Anna Ivanchenko
Department of Chemistry, Lomonosov Moscow State University, 119991, Leniskie gory 1-3, Moscow, Russia
Oleg Morozov
Department of Chemistry, Lomonosov Moscow State University, 119991, Leniskie gory 1-3, Moscow, Russia
Aslan Miriyev
Materials and Technology Center of Robotics, Empa- Swiss Federal Laboratories for Materials Science and Technology, Ueberlandst. 129, Dübendorf 8600, Switzerland
Indrek Must
Intelligent Materials and Systems Lab, Institute of Technology, University of Tartu, Nooruse 1, 50411 Tartu, Estonia
Oskars Platnieks
Faculty of Materials Science and Applied Chemistry, Institute of Polymer Materials, Riga Technical University, P.Valdena 3/7, Riga LV-1048, Latvia
Maksims Jurinovs
Faculty of Materials Science and Applied Chemistry, Institute of Polymer Materials, Riga Technical University, P.Valdena 3/7, Riga LV-1048, Latvia
Sergejs Gaidukovs
Faculty of Materials Science and Applied Chemistry, Institute of Polymer Materials, Riga Technical University, P.Valdena 3/7, Riga LV-1048, Latvia
Alvo Aabloo
Intelligent Materials and Systems Lab, Institute of Technology, University of Tartu, Nooruse 1, 50411 Tartu, Estonia
Mirko Kovač
Materials and Technology Center of Robotics, Empa- Swiss Federal Laboratories for Materials Science and Technology, Ueberlandst. 129, Dübendorf 8600, Switzerland
Boris Bulgakov
Department of Chemistry, Lomonosov Moscow State University, 119991, Leniskie gory 1-3, Moscow, Russia
Here we show the effect of the ionic liquid nature, its content and monomer/crosslinker ratio on the copolymerization of N-vinylpyrrolidone (NVP) with triethylene glycol dimethacrylate (TEGDMA) induced by UV or heat irradiation. For the first time, kinetics curves of photopolymerization NVP with TEGDMA in the presence of ionic liquids are obtained. The ionic liquids EmimBF4, BmimBF4, OmimBF4 and EmimTFSI with different cation and anion structures and lengths of the alkyl radical were varied in photopolymer compositions. To understand the influence of ionic liquids on the polymerization kinetics, photo-DSC, dynamic DSC, and FTIR were performed. Parameters obtained from photo-DSC curves allowed to develop the methodology for the stereolithography of ionogels. The presented data constitutes the complete dataset useful for 3D-printing of ionogels with high accuracy, which is reported in the main article.
