Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
Ramón Azpíroz,
Mert Olgun Karataş,
Vincenzo Passarelli,
Ismail Özdemir,
Jesús J. Pérez-Torrente,
Ricardo Castarlenas
Affiliations
Ramón Azpíroz
Departamento de Química Inorgánica—Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza—CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Mert Olgun Karataş
Departamento de Química Inorgánica—Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza—CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Vincenzo Passarelli
Departamento de Química Inorgánica—Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza—CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Ismail Özdemir
Department of Chemistry, Faculty of Sciences, Inonu University, 44280 Malatya, Turkey
Jesús J. Pérez-Torrente
Departamento de Química Inorgánica—Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza—CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Ricardo Castarlenas
Departamento de Química Inorgánica—Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza—CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ligands and the η2-olefin is critical. Similarly, new mixed coumarin-functionalized bis-NHC rhodium complexes have been prepared by a reaction of mono NHC complexes of type RhCl(NHC-coumarin)(η2,η2-cod) with the corresponding azolium salt in the presence of an external base. Both synthetic procedures proceed selectively and allow the preparation of mixed bis-NHC rhodium complexes in good yields.
