Acta Crystallographica Section E (Sep 2009)

Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III)

  • R. Reshma,
  • P. V. Soumya,
  • S. M. Simi,
  • V. S. Thampidas,
  • Robert D. Pike

DOI
https://doi.org/10.1107/S1600536809032553
Journal volume & issue
Vol. 65, no. 9
pp. m1110 – m1111

Abstract

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The title compound, [Mn(C18H18N2O4)(C7H5O3)(H2O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxysalicylaldehyde in presence of manganese(II) 4-hydroxybenzoate. The Jahn–Teller-distorted manganese(III) centre has an octahedral geometry. Extensive O—H...O hydrogen-bonding interactions generate a two-dimensional sheet structure parallel to (103).