Preparation of Anti-Bacterial Cellulose Nanofibrils (CNFs) from Bamboo Pulp in a Reactable Citric Acid–Choline Chloride Deep Eutectic Solvent

Yuanchen Zhu; Jinhui Zhang; Dawei Wang; Zhengjun Shi; Jing Yang; Haiyan Yang

doi:10.3390/polym15010148

Polymers (Dec 2022)

Preparation of Anti-Bacterial Cellulose Nanofibrils (CNFs) from Bamboo Pulp in a Reactable Citric Acid–Choline Chloride Deep Eutectic Solvent

Yuanchen Zhu,
Jinhui Zhang,
Dawei Wang,
Zhengjun Shi,
Jing Yang,
Haiyan Yang

Affiliations

Yuanchen Zhu: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
Jinhui Zhang: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
Dawei Wang: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
Zhengjun Shi: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
Jing Yang: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
Haiyan Yang: Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

DOI: https://doi.org/10.3390/polym15010148
Journal volume & issue: Vol. 15, no. 1
p. 148

Abstract

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In this study, bamboo pulp was simultaneously fibrillated and esterified in one-pot citric acid–choline chloride deep eutectic solvent treatment. The results indicated that increasing the temperature and time promoted esterification, yielding 0.19 to 0.35 mmol/g of the carboxyl group in CNFs. However, increasing the temperature and time resulted in decreases in yields and the diameter of CNFs from 84.5 to 66.6% and 12 to 4 nm, respectively. Analysis of the anti-bacterial activities of CNFs suggested that the high carboxyl group content corresponded to the effective inhibition of Escherichia coli and Staphylococcus aureus Taking yield, size, carboxyl group content, and anti-bacterial activate into consideration, treatment at 120 °C for 24 h was the optimal condition, yielding 76.0% CNF with 0.31 mmol/g carboxyl groups with a diameter of 8 nm and the inhibition fof E. coli (81.7%) and S. aureus (63.1%). In addition, effect of different CNFs on characteristics of polyvinyl alcohol (PVA) films were investigated. The results indicated that CNF obtained from the optimal condition was a favorable additive for the composite film, which enhanced (74%) the tensile strength of composite film compared with the pure PVA film due to its considerable size and carboxyl group content. However, the composite films did not show an anti-bacterial activate as CNF.

Published in Polymers

ISSN: 2073-4360 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/polymers/

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