Removal of Aqueous Antimony and Arsenic by Iron-Loaded Coal Gasification Slag Composite

Abstract

The adsorption of Sb(V) and As(V) onto iron-loaded gasification slag composite material (Fe-GFS), as well as the possible mechanisms, was investigated. Batch experiments showed that in a single system, Fe-GFS sorbed As(V) to a greater extent than Sb(V) with the maximum adsorption capacity (pH 3.0) of 34.99 mg/g (0.47 mmol/g), while that of Sb(V) was 27.61 mg/g (0.23 mmol/g). In the composite system, the presence of low concentrations of Sb(V) reduced the adsorption efficiency of Fe-GFS for As(V), while the presence of high concentrations of Sb(V) actually promoted the adsorption of As(V). The presence of As(V) consistently inhibited the adsorption of Sb(V) by Fe-GFS. Compared to Fe-GFS, new peaks appeared in the FTIR spectra after adsorption, indicating the presence of Sb-O and As-O bonds on the surface after adsorption. XPS results showed that the adsorption of As(V) and Sb(V) led to a decrease in Fe-OH bonds, with a more significant decrease in Fe-OH bonds observed after the adsorption of As(V), indicating a stronger affinity of Fe-GFS for As(V) compared to Sb(V). Our results suggest that Fe-GFS is an efficient adsorbent with great potential for applications in water containing As(V) and Sb(V).

Keywords

• iron-loaded coal gasification slag
• arsenic
• antimony
• FeOOH
• adsorption