Utilizing CaCl2 to promote the enrichment and bioavailability of phosphorus in incinerated sludge ash

Abstract

Recovering phosphorus from incineration sludge sewage ash (ISSA) is a well-established technology, with a greater recovery potential than that of supernatant or sludge. ISSA can be utilized as a secondary raw material in the fertilizer industry, or as a fertilizer if heavy metal concentrations do not exceed permissible limits, thus reducing the cost of phosphorus recovery. Increasing the temperature to produce ISSA with higher solubility and plant availability of phosphorus is advantageous for both pathways. But a decrease in the extraction of phosphorus is also observed at high temperatures, thereby diminishing the overall economic benefits. In this study, CaCl2 was utilized to mitigate the decrease in the extraction rate and also to promote the bioavailability of phosphorus. The addition of CaCl2 (80 g/kg of dry sludge) effectively promoted the conversion of non-apatite inorganic phosphorus to apatite inorganic phosphorus at a rate of 87.73% at 750 °C. Furthermore, the decrease in the extraction rate of phosphorus at 1,050 °C was comparatively smaller in the presence of CaCl2. If iron flocculants are used to capture P in wastewater management, it may be necessary to pay special attention to the amount of addition and incineration temperature to maximize the economic potential of recycling. HIGHLIGHTS The decrease in the extraction of phosphorus at high temperatures is due to the enwrapping of some phosphorus-containing minerals by molten phases.; The decrease in the extraction of phosphorus in sludge ash at high temperatures is mitigated by CaCl2.; The acceptable conversion rate of apatite inorganic phosphorus (87%) can be achieved at 750 °C with a Ca/P ratio of 2.0.;

Keywords

• phosphorus form
• recovery
• sintering
• sludge ash
• waste treatment