³¹P NMR Investigations on Roundup Degradation by AOP Procedures

Abstract

The reactions of (N-(PhosphonoMethyl)Glycine) PMG with H2O2 in homogenous systems were investigated using 31P NMR (Nuclear Magnetic Resonance). These reactions were carried out in two reaction modes: without UV radiation and under UV radiation. The reactions of PMG with H2O2 without UV radiation were carried out in two modes: the degradations of PMG (0.1 mmol) by means of 5⁻10 molar excess of hydrogen dioxide (PMG-H2O2 = 1:5 and 1:10) and the degradation of PMG (0.1 mmol) in homogenous Fenton reactions (PMG-H2O2-Fe2+ = 1:10:0.05 and 1:10:0.1). All reactions were carried out at ambient temperature, at pH 3.5, for 48 h. The reactions of PMG (in Roundup herbicide composition, 12 mmol) with H2O2 under UV radiation (254 nm) were carried out using 5 × molar excess of H2O2 (60 mmol), in the pH range of 2 ≤ pH ≤ 12, for 6 h. In this mode of PMG oxidation, the splitting of C-P was observed in the ratios dependent on the applied pH of the reaction mixture.

Keywords

• glyphosate
• oxidation stability
• oxidative dephosphonylation
• Fenton reaction