Efficient removal of ammonia–nitrogen in wastewater by zeolite molecular sieves prepared from coal fly ash

Abstract

Abstract Zeolite molecular sieves are potential adsorbents for wastewater treatment, characterized by high efficiency, simple process, easy regeneration, and low treatment cost. In this study, zeolite A molecular sieves were prepared using coal fly ash (CFA), which is an effective method for the utilization of CFA. The results showed that the CFA-based zeolite molecular sieves synthesized under optimized conditions exhibited excellent adsorption and removal rates (> 40%) for ammonia–nitrogen in wastewater of different concentrations and properties. The analysis of adsorption kinetics revealed that the adsorption process followed pseudo-second-order kinetics model, indicating that the adsorption of ammonia–nitrogen on zeolite is primarily controlled by chemisorption rather than physisorption. The adsorption process can be divided into two stages, with a higher adsorption rate and a smaller diffusion boundary layer thickness in the first stage, and a lower adsorption rate and an increased diffusion boundary layer thickness in the second stage. This indicates that as the adsorption proceeds, the internal diffusion resistance within the particles gradually increases, leading to a decrease in the adsorption rate until reaching equilibrium, where both the diffusion and adsorption become stable. The adsorption isotherms of ammonia–nitrogen on zeolite A conformed to the assumptions of the Langmuir model, suggesting that the adsorption mechanism primarily involves uniform monolayer adsorption on the surface without intermolecular interactions.

Keywords

• Zeolite molecular sieves
• Coal fly ash
• Adsorption
• Wastewater treatment
• Ammonia–nitrogen