Journal of Analytical Science and Technology (Dec 2011)

Acidity of Solid and Liquid Acids Probed by P-31 NMR Chemical Shifts of Phosphine Oxides

  • Chih-Yi Yang,
  • Chih-Chung Chang,
  • Ningdong Feng,
  • Shing-Jong Huang,
  • Anmin Zheng,
  • Yu-Chi Chang,
  • Kuei-Chi Lee,
  • Feng Deng,
  • Shang-Bin Liu

Journal volume & issue
Vol. 2, no. Supplement A
pp. A155 – A158

Abstract

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A novel method for acidity characterization of solid and liquid acids is proposed. Surpassing conventional methods, this technique employs 31P nuclear magnetic resonance (NMR) of adsorbed phosphine oxides is capable of monitoring a wide range of acidic strengths from weak to super acids with superior sensitivity.

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