Acta Crystallographica Section E (Aug 2010)
2-Bromo-2-methyl-N-(4-methyl-2-oxo-2H-chromen-7-yl)propanamide
Abstract
In the title compound C14H14BrNO3, the coumarin ring system is almost planar (r.m.s. deviation = 0.008 Å) and an intramolecular C—H...O interaction generates an S(6) ring. In the crystal, molecules are linked by N—H...O hydrogen bonds, with the C=O unit of the coumarin ring system acting as the acceptor group, generating [010] C(8) chains. The chain connectivity is reinforced by two C—H...O interactions.