Nanomaterials (Jan 2021)

Femtosecond Laser-Induced Periodic Surface Structures on 2D Ti-Fe Multilayer Condensates

  • Oleksandr V. Kuznietsov,
  • George D. Tsibidis,
  • Anatoliy V. Demchishin,
  • Anatoliy A. Demchishin,
  • Volodymyr Babizhetskyy,
  • Ivan Saldan,
  • Stefano Bellucci,
  • Iaroslav Gnilitskyi

DOI
https://doi.org/10.3390/nano11020316
Journal volume & issue
Vol. 11, no. 2
p. 316

Abstract

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2D Ti-Fe multilayer preparation has been attracting increased interest due to its ability to form intermetallic compounds between metallic titanium and metallic iron thin layers. In particular, the TiFe compound can absorb hydrogen gas at room temperature. We applied femtosecond laser pulses to heat Ti-Fe multilayer structures to promote the appearance of intermetallic compounds and generate surface nanostructuring. The surface pattern, known as Laser Induced Periodic Surface Structures (LIPSS), can accelerate the kinetics of chemical interaction between solid TiFe and gaseous hydrogen. The formation of LIPSS on Ti-Fe multilayered thin films were investigated using of scanning electron microscopy, photo-electron spectroscopy and X-ray diffraction. To explore the thermal response of the multiple layered structure and the mechanisms leading to surface patterning after irradiating the compound with single laser pulses, theoretical simulations were conducted to interpret the experimental observations.

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