Acta Crystallographica Section E (Aug 2010)

2,10-Bis(3-bromophenyl)-3,7,11,15-tetraoxa-8,16-diazatricyclo[12.2.1.16,9]octadeca-1(16),6(18),8,14(17)-tetraene

  • Kwang Ha,
  • Sae Byul Park,
  • Young Ju Lee,
  • Hyung Jin Kim

DOI
https://doi.org/10.1107/S1600536810028813
Journal volume & issue
Vol. 66, no. 8
pp. o2120 – o2120

Abstract

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The title compound, C24H20Br2N2O4, is an 18-membered tricycle including two isoxazole rings. The asymmetric unit contains one half of the formula unit; a centre of inversion is located at the centroid of the compound. The dihedral angle between adjacent isoxazole and benzene rings is 84.0 (2)°. The compound displays intra- and intermolecular π–π stacking interactions between the isoxazole rings, the shortest centroid–centroid distances being 3.837 (3) and 3.634 (3) Å, respectively. The molecules are stacked in columns along the a axis with short Br...Br contacts [3.508 (1) Å].