A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS<sub>2</sub> Cathode Catalysts
Min Wang,
Xiaoxiao Huang,
Zhiqian Yu,
Pei Zhang,
Chunyang Zhai,
Hucheng Song,
Jun Xu,
Kunji Chen
Affiliations
Min Wang
National Laboratory of Solid State Microstructures, School of Electronics Science and Engineering, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Xiaoxiao Huang
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
Zhiqian Yu
National Laboratory of Solid State Microstructures, School of Electronics Science and Engineering, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Pei Zhang
College of Electrical and Information Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China
Chunyang Zhai
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
Hucheng Song
National Laboratory of Solid State Microstructures, School of Electronics Science and Engineering, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Jun Xu
National Laboratory of Solid State Microstructures, School of Electronics Science and Engineering, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Kunji Chen
National Laboratory of Solid State Microstructures, School of Electronics Science and Engineering, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
Aqueous rechargeable zinc (Zn)–air batteries have recently attracted extensive research interest due to their low cost, environmental benignity, safety, and high energy density. However, the sluggish kinetics of oxygen (O2) evolution reaction (OER) and the oxygen reduction reaction (ORR) of cathode catalysts in the batteries result in the high over-potential that impedes the practical application of Zn–air batteries. Here, we report a stable rechargeable aqueous Zn–air battery by use of a heterogeneous two-dimensional molybdenum sulfide (2D MoS2) cathode catalyst that consists of a heterogeneous interface and defects-embedded active edge sites. Compared to commercial Pt/C-RuO2, the low cost MoS2 cathode catalyst shows decent oxygen evolution and acceptable oxygen reduction catalytic activity. The assembled aqueous Zn–air battery using hybrid MoS2 catalysts demonstrates a specific capacity of 330 mAh g−1 and a durability of 500 cycles (~180 h) at 0.5 mA cm−2. In particular, the hybrid MoS2 catalysts outperform commercial Pt/C in the practically meaningful high-current region (>5 mA cm−2). This work paves the way for research on improving the performance of aqueous Zn–air batteries by constructing their own heterogeneous surfaces or interfaces instead of constructing bifunctional catalysts by compounding other materials.
