Nature Communications (Jan 2020)

Biobased chiral semi-crystalline or amorphous high-performance polyamides and their scalable stereoselective synthesis

  • Paul N. Stockmann,
  • Daniel Van Opdenbosch,
  • Alexander Poethig,
  • Dominik L. Pastoetter,
  • Moritz Hoehenberger,
  • Sebastian Lessig,
  • Johannes Raab,
  • Marion Woelbing,
  • Claudia Falcke,
  • Malte Winnacker,
  • Cordt Zollfrank,
  • Harald Strittmatter,
  • Volker Sieber

DOI
https://doi.org/10.1038/s41467-020-14361-6
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 12

Abstract

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Bio‐based compounds often suffer from high production cost and low performance when used to synthesise macromolecules. Here the authors show the conversion of (+)‐3‐ carene, a by‐product of the cellulose industry, into its ε‐lactams and then to polyamides with high‐performance thermal properties.