Materials for Quantum Technology (Jan 2024)

XPS analysis of molecular contamination and sp2 amorphous carbon on oxidized (100) diamond

  • Ricardo Vidrio,
  • Daniel Vincent,
  • Benjamin Bachman,
  • Cesar Saucedo,
  • Maryam Zahedian,
  • Zihong Xu,
  • Junyu Lai,
  • Timothy A Grotjohn,
  • Shimon Kolkowitz,
  • Jung-Hun Seo,
  • Robert J Hamers,
  • Keith G Ray,
  • Zhenqiang Ma,
  • Jennifer T Choy

DOI
https://doi.org/10.1088/2633-4356/ad4e8a
Journal volume & issue
Vol. 4, no. 2
p. 025201

Abstract

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The efficacy of oxygen (O) surface terminations on diamond is an important factor for the performance and stability for diamond-based quantum sensors and electronics. Given the wide breadth of O-termination techniques, it can be difficult to discern which method would yield the highest and most consistent O coverage. Furthermore, the interpretation of surface characterization techniques is complicated by surface morphology and purity, which if not accounted for will yield inconsistent determination of the oxygen coverage. We present a comprehensive approach to consistently prepare and analyze oxygen termination of surfaces on (100) single-crystalline diamond. We report on x-ray photoelectron spectroscopy (XPS) characterization of diamond surfaces treated with six oxidation methods that include various wet chemical oxidation techniques, photochemical oxidation with UV illumination, and steam oxidation using atomic layer deposition (ALD). Our analysis entails a rigorous XPS peak-fitting procedure for measuring the functionalization of O-terminated diamond. The findings herein have provided molecular-level insights on oxidized surfaces in (100) diamond, including the demonstration of clear correlation between the measured oxygen atomic percentage and the presence of molecular contaminants containing nitrogen, silicon, and sulfur. We also provide a comparison of the sp ^2 carbon content with the O1s atomic percentage and discern a correlation with the diamond samples treated with dry oxidation which eventually tapers off at a max O1s atomic percentage value of 7.09 ± 0.40%. Given these results, we conclude that the dry oxidation methods yield some of the highest oxygen amounts, with the ALD water vapor technique proving to be the cleanest technique out of all the oxidation methods explored in this work.

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