A Review of Persulfate Activation by Magnetic Catalysts to Degrade Organic Contaminants: Mechanisms and Applications

Abstract

All kinds of refractory organic pollutants in environmental water pose a serious threat to human health and ecosystems. In recent decades, sulfate radical-based advanced oxidation processes (SR-AOPs) have attracted extensive attention in the removal of these organic pollutants due to their high redox potential and unique selectivity. This review first introduces persulfate activation by magnetic catalysts to degrade organic contaminants. We present the advances and classifications in the generation of sulfate radicals using magnetic catalysts. Subsequently, the degradation mechanisms in magnetic catalysts activated persulfate system are summarized and discussed. After an integrated presentation of magnetic catalysts in SR-AOPs, we discuss the application of persulfate activation by magnetic catalysts in the treatment of wastewater, landfill leachate, biological waste sludge, and soil containing organic pollutants. Finally, the current challenges and perspectives of magnetic catalysts that activated persulfate systems are summarized and put forward.

Keywords

• magnetic catalysts
• persulfate activation
• radical pathway
• non-radical pathway
• mechanism and application