On the Relations between Lithium-Ion Battery Reaction Entropy, Surface Temperatures and Degradation

Abstract

Understanding and mitigating the degradation of batteries is important for financial as well as environmental reasons. Many studies look at cell degradation in terms of capacity losses and the mechanisms causing them. However, in this study, we take a closer look at how degradation affects heat sources in batteries, thereby requiring dynamic cooling strategies for battery systems throughout the battery life. In this work, we have studied and compared reversible (entropy-related) and non-reversible heat sources in a commercial LCO-graphite lithium-ion battery (LIB) alongside measuring the surface temperature as a function of the State of Health (SoH). In addition, we studied the effect of different thermal management strategies on both degradation and cooling efficiency. We found that entropic heating plays a major role in overall heat generation. This causes large variations in heat generation and battery temperature over both State of Charge (SoC) and charge versus discharge. The maximum battery temperature increases when the cell degrades as irreversible heat generation increases. Temperature variations over the cell thickness are substantial and increase drastically when the cell degrades. In addition, significant increases in thickness were observed as a result of cell degradation. Furthermore, cycling at elevated temperatures resulted in a larger thickness increase with significant gas production.

Keywords

• LIB
• degradation
• heat generation
• entropy