Synthesis of Fe–Ni–TiO2/activated carbon nanoparticles and evaluation of catalytic activity in a palm oil/diesel fuel blended diesel engine and optimization with RSM

Abstract

Although diesel engine emissions, which can pose serious risks to the environment and human health, can be reduced with biodiesel/diesel fuel blends, combining diesel fuel with an oxidation catalyst with a sizable oxygen storage capacity can more effectively reduce emissions from diesel engines. In this study, Fe–Ni–TiO2/Activated Carbon (AC) catalyst was produced and used as an oxidation catalyst. Experimental studies were performed on a four-stroke diesel engine by adding at numerous concentrations (0–50–100 ppm) Fe–Ni–TiO2/AC nanoparticles (NP) to the Palm Oil biodiesel (PO)-diesel fuel blend. Optimum conditions were determined by modelling the obtained data in response surface methodology (RSM). The Fe–Ni–TiO2/AC catalyst outcomes in a considerable decrease in hydrocarbon (HC), nitrogen oxides (NOx), carbon monoxide (CO), and smoke emissions. Optimization outcomes pointed out that the ideal diesel engine running requirements were determined to be 1750 W engine load, 100 ppm the NP amount, and 30% the PO ratio. Responses for these optimum conditions for Brake Specific Fuel Consumption (BSFC), Brake Thermal Efficiency (BTHE), CO, HC, NOx, and smoke were determined as 999.06 g/kWh, 27.07%, 0.032%, 40.63 ppm, 818.18 ppm, and 4.26%, respectively. The R2 values showed that the result obtained from the created model was in good agreement with the experimental results.

Keywords

• nanoparticles
• palm oil biodiesel
• catalyst
• emission
• response surface methodology