Acta Crystallographica Section E (Jan 2008)

[N,N′-Bis(4-chlorobenzyl)ethane-1,2-diamine]dichloridozinc(II)

  • Shu-Ping Yang,
  • Li-Jun Han,
  • Da-Qi Wang,
  • Hai-Tao Xia

DOI
https://doi.org/10.1107/S1600536807063088
Journal volume & issue
Vol. 64, no. 1
pp. m62 – m62

Abstract

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In the title complex, [ZnCl2(C16H18Cl2N2)], the asymmetric unit contains one molecule and two half-molecules, which have similar geometric parameters; in the latter two molecules each Zn atom lies on a twofold rotation axis. The environment about each ZnII atom is distorted tetrahedral with coordination of two terminal Cl atoms and two N atoms of the N,N′-bis(4-chlorobenzyl)ethane-1,2-diamine ligand. Four N—H...Cl hydrogen bonds link the molecules into a chain of R22(8) rings in the [001] direction.