Alloy design for microstructural-tailored boron-modified ferritic stainless steel to ensure corrosion and wear resistance

Abstract

Ferritic stainless steels armored with borides had their endurance tested in demanding both abrasive and corrosive environment. The degradation was investigated through a very aggressive plate-on-cylinder wear test in water-based drilling mud containing chlorides, which was designed to simulate, in laboratorial scale, the corrosive tribosystem found in the wear of risers and casings used in deep water oil exploitation. A commercially-grade 430 ferritic stainless steel containing boron content far beyond its solubility limity, namely 1.2 and 3.5 wt.%, was processed by spray-forming to induce a ferritic stainless steel matrix protected by a boride skeleton. Additional corrosion assessment was performed by potentiodynamic polarization and electrochemical impedance spectroscopy in 0.27 M KCl solution, since KCl is a common clay swelling inhibitor. For comparison, API 5L X80 steel was also included since this material is used in risers and casings manufacture. The addition of boron (1.2 and 3.5 wt.%) led to the formation of microstructures composed of an α-ferrite matrix with homogeneously distributed M2B-type borides of different morphologies. Electrochemical tests revealed high corrosion resistance of the alloy with 1.2 wt.% B. However, the alloy with 3.5 wt.% B showed a considerable decrease in corrosion resistance due to Cr-depletion of the ferritic matrix given the M2B formation richer in Cr. Therefore, the alloy with 1.2 wt.% B offered the best tribocorrosion resistance.

Keywords

• Stainless steel
• Spray forming
• CALPHAD method
• Solidification
• Tribocorrosion