Influence of Meteorological Factors and Chemical Processes on the Explosive Growth of PM_2.5 in Shanghai, China

Abstract

In order to explore the mechanism of haze formation, the meteorological effect and chemical reaction process of the explosive growth (EG) of PM2.5 were studied. In this study, the level of PM2.5, water-soluble inorganic ions, carbonaceous aerosols, gaseous precursors, and meteorological factors were analyzed in Shanghai in 2018. The EG event is defined by a net increase of PM2.5 mass concentration greater than or equal to 100 μg m−3 within 3, 6, or 9 h. The results showed that the annual average PM2.5 concentration in Shanghai in 2018 was 43.2 μg m−3, and secondary inorganic aerosols and organic matter (OM) accounted for 55.8% and 20.1% of PM2.5, respectively. The increase and decrease in the contributions of sulfate, nitrate, ammonium (SNA), and elemental carbon (EC) to PM2.5 from clean days to EG, respectively, indicated a strong, secondary transformation during EG. Three EG episodes (Ep) were studied in detail, and the PM2.5 concentration in Ep3 was highest (135.7 μg m−3), followed by Ep2 (129.6 μg m−3), and Ep1 (82.3 μg m−3). The EG was driven by stagnant conditions and chemical reactions (heterogeneous and gas-phase oxidation reactions). This study improves our understanding of the mechanism of haze pollution and provides a scientific basis for air pollution control in Shanghai.

Keywords

• fine particle
• explosive growth
• mechanism
• meteorological factors
• chemical reaction process