Scientific Reports (Sep 2023)

RETRACTED ARTICLE: Synthesis and characterization of ZrFe2O4@SiO2@Ade-Pd as a novel, recyclable, green, and versatile catalyst for Buchwald–Hartwig and Suzuki–Miyaura cross-coupling reactions

  • Mohamed J. Saadh,
  • Hussam Elddin Nabieh Khasawneh,
  • Geovanny Genaro Reivan Ortiz,
  • Muhammad Ahsan,
  • Dinesh Kumar Sain,
  • Kareem Yusuf,
  • Mika Sillanää,
  • Amjad Iqbal,
  • Reza Akhavan-Sigari

DOI
https://doi.org/10.1038/s41598-023-37680-2
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 16

Abstract

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Abstract This work presents the simple synthesis of a green and novel Palladium based magnetic nanocatalyst with effective catalytic properties and reusability. These heterogeneous catalysts were prepared by the anchoring of Pd(0) on the surface of ZrFe2O4 MNPs coated with a di-substituted adenine (Ade) compound as a green linker. The as-synthesized ZrFe2O4@SiO2@Ade-Pd MNPs were methodically characterized over different physicochemical measures like VSM, EDX, Map, SEM, TEM, ICP, and FT-IR analysis. The catalytic activity of ZrFe2O4@SiO2@Ade-Pd was carefully examined for the room-temperature Carbon–Carbon coupling reaction in acetonitrile as a solvent. It is worth noting that the synthesized solid catalyst can be easily recovered with a bar magnet and reused for five cycles without decrease of catalytic activity.