We perform dielectric and impedance spectrums on the compressively-strained ceramics of multiferroic bismuth ferrite. The subsurface-nanolayer quasipolarons manifest the step-like characteristic of pressure-dependent transient frequency and, furthermore, pressure-dependency fails in the transformation between complex permittivity and electrical impedance, which is well-known in classic dielectric physics, as well as the bulk dipole chain at the end of the dissipation peak.
