Chemical Engineering Journal Advances (Mar 2025)

Recent advancement and design in supercapacitor hybrid electrode materials: Bridging the gap between energy and power density

  • Soumen Mandal,
  • Arpit B. Mendhe,
  • Hitesh M. Rakhade,
  • Neha S. Barse,
  • Mayna Roy,
  • P. Rosaiah,
  • Taejoon Park,
  • Han-Seung Lee,
  • Avinash C. Mendhe,
  • Daewon Kim

Journal volume & issue
Vol. 21
p. 100690

Abstract

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Supercapacitors (SCs) are becoming more crucial for alternative energy storage because of their high-power density, quick charge and discharge rates, and lasting cycle life. As global energy demand upsurges and environmental concerns over fossil fuel consumption intensify, the need for efficient, sustainable energy storage systems is greater than ever. This inclusive review explores the fundamentals of SC technology, including design elements, key components, and recent advancements in materials engineering aimed at enhancing performance. Special attention is given to the importance of electrode materials, as they play a crucial role in the cost efficiency and electrochemical performance of SCs. Advances in material modifications such as the integration of nanomaterials are analyzed, with a focus on their ability to improve energy density and cycling stability. Additionally, the review assesses various types of electrode materials such as carbon-based, metal oxide-based, conducting polymers, and metal chalcogenide-based electrodes, in combination with nanomaterials like carbon, metal oxides, among others. While batteries offer superior energy density, SCs have better power density, making them ideal for applications that demand rapid power supply, like electric vehicles and portable electronics. This review also addresses the challenges in balancing energy density and stability, highlighting promising modifications and nanostructures that are pushing SC technology forward. Finally, insights into hybrid and asymmetric supercapacitors are presented, offering practical guidelines for researchers and engineers in the field to enhance SC performance and facilitate their broader adoption in renewable energy systems.

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