Dilational Rheology of Fluid/Fluid Interfaces: Foundations and Tools

Abstract

Fluid/fluid interfaces are ubiquitous in science and technology, and hence, the understanding of their properties presents a paramount importance for developing a broad range of soft interface dominated materials, but also for the elucidation of different problems with biological and medical relevance. However, the highly dynamic character of fluid/fluid interfaces makes shedding light on fundamental features guiding the performance of the interfaces very complicated. Therefore, the study of fluid/fluid interfaces cannot be limited to an equilibrium perspective, as there exists an undeniable necessity to face the study of the deformation and flow of these systems under the application of mechanical stresses, i.e., their interfacial rheology. This is a multidisciplinary challenge that has been evolving fast in recent years, and there is currently available a broad range of experimental and theoretical methodologies providing accurate information of the response of fluid/fluid interfaces under the application of mechanical stresses, mainly dilational and shear. This review focused on providing an updated perspective on the study of the response of fluid/fluid interfaces to dilational stresses; to open up new avenues that enable the exploitation of interfacial dilational rheology and to shed light on different problems in the interest of science and technology.

Keywords

• area
• compression
• dilation
• expansion
• interfaces
• rheology