Tandem utilization of CO2 photoreduction products for the carbonylation of aryl iodides

Yuan-Sheng Xia; Meizhong Tang; Lei Zhang; Jiang Liu; Cheng Jiang; Guang-Kuo Gao; Long-Zhang Dong; Lan-Gui Xie; Ya-Qian Lan

doi:10.1038/s41467-022-30676-y

Nature Communications (May 2022)

Tandem utilization of CO2 photoreduction products for the carbonylation of aryl iodides

Yuan-Sheng Xia,
Meizhong Tang,
Lei Zhang,
Jiang Liu,
Cheng Jiang,
Guang-Kuo Gao,
Long-Zhang Dong,
Lan-Gui Xie,
Ya-Qian Lan

Affiliations

Yuan-Sheng Xia: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Meizhong Tang: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Lei Zhang: School of Chemistry, South China Normal University
Jiang Liu: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Cheng Jiang: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Guang-Kuo Gao: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Long-Zhang Dong: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Lan-Gui Xie: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University
Ya-Qian Lan: Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University

DOI: https://doi.org/10.1038/s41467-022-30676-y
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 12

Abstract

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A Ni-based MOF catalyst is reported to facilitate the photocatalytic reduction of CO2 to CO, a low-value product. In tandem, the as-produced CO is used as a reactant in the Pd-catalyzed carbonylation of aryl halides and other fine organic chemicals.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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