Preparation of an activated adsorbent from water treatment plant sludge for phosphate removal from wastewater: optimization, characterization, isotherm, and kinetics studies

Abstract

Purifying water for diverse uses is vital, but concerns lie with the sustainability and accessibility of purification materials. As such, this study converted readily available water treatment plant sludge (WTPS) into activated adsorbent for phosphate removal in wastewater. WTPS was activated via thermal activation at 300 °C temperature and chemical activation processes of 3 M acid concentration, 4 h activation time, and 75 °C activation temperature, and then characterized using Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared, elemental analyzer, and differential scanning calorimetry. SEM and BET analyses revealed a highly porous adsorbent (279.2 m2/g) for efficient adsorption. On top of the activation process, preliminary experiments and numerical optimization using response surface methodology (RSM) were designed and conducted. Through optimizing conditions, it was found that 70 min of contact time, pH 3, 3 g/L adsorbent dose, and 30 mg/L initial phosphate concentration as optimal, yielding 83% removal efficiency. Furthermore, adsorption kinetics and isotherm models were examined and the second-order kinetics and Langmuir isotherm models indicated best fit. Notably, the activated sludge could be regenerated for three cycles before efficiency dropped below 70%. Thus, activated WTPS presents a promising, sustainable, and readily available adsorbent for phosphate removal in wastewater treatment. HIGHLIGHTS Water treatment plant sludge (WTPS) was activated through thermal activation and chemical activation.; The activated WTPS adsorbent has a surface area of 279.2 m2/g.; The activated WTPS showed an 83% removal efficiency.; The regeneration test indicated that the activated sludge can be used three times, repeatedly, before its efficacy falls below 70%.;

Keywords

• activation
• adsorption
• kinetics study
• optimization
• water treatment plant sludge