Strain-Induced Surface Interface Dual Polarization Constructs PML-Cu/Bi12O17Br2 High-Density Active Sites for CO2 Photoreduction

Yi Zhang; Fangyu Guo; Jun Di; Keke Wang; Molly Meng-Jung Li; Jiayu Dai; Yuanbin She; Jiexiang Xia; Huaming Li

doi:10.1007/s40820-023-01309-w

Nano-Micro Letters (Jan 2024)

Strain-Induced Surface Interface Dual Polarization Constructs PML-Cu/Bi12O17Br2 High-Density Active Sites for CO2 Photoreduction

Yi Zhang,
Fangyu Guo,
Jun Di,
Keke Wang,
Molly Meng-Jung Li,
Jiayu Dai,
Yuanbin She,
Jiexiang Xia,
Huaming Li

Affiliations

Yi Zhang: School of Chemistry and Chemical Engineering, Institute for Energy Research, School of the Environment and Safety Engineering, Jiangsu University
Fangyu Guo: College of Science, and Hunan Key Laboratory of Extreme Matter and Applications, National University of Defense Technology
Jun Di: School of Chemistry and Chemical Engineering, National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology
Keke Wang: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology
Molly Meng-Jung Li: Department of Applied Physics, The Hong Kong Polytechnic University
Jiayu Dai: College of Science, and Hunan Key Laboratory of Extreme Matter and Applications, National University of Defense Technology
Yuanbin She: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology
Jiexiang Xia: School of Chemistry and Chemical Engineering, Institute for Energy Research, School of the Environment and Safety Engineering, Jiangsu University
Huaming Li: School of Chemistry and Chemical Engineering, Institute for Energy Research, School of the Environment and Safety Engineering, Jiangsu University

DOI: https://doi.org/10.1007/s40820-023-01309-w
Journal volume & issue: Vol. 16, no. 1
pp. 1 – 15

Abstract

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Highlights Strain induces coupling in Bi12O17Br2 and Cu porphyrin-based monoatomic layer (PML-Cu), constructing Bi–O bonding interface in PML-Cu/BOB (PBOB). Surface interface dual polarization boosts internal electric field, promoting electron transfer. PML-Cu provides high density of dispersed active Cu sites in PBOB, enhancing CO2 photoreduction.

Published in Nano-Micro Letters

ISSN: 2311-6706 (Print); 2150-5551 (Online)
Publisher: SpringerOpen
Country of publisher: Germany
LCC subjects: Technology
Website: http://www.springer.com/40820

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