Effects of Y substituting Gd on the microstructure evolution, mechanical properties and dissolution behaviors in the Mg-Gd-Ni alloys used as fracturing plugging tools

Abstract

In this work, the effects of substituting 3 wt% Gd with 3 wt% Y on the microstructure, mechanical properties, and corrosion behaviors in the Mg-Gd-Ni alloys were investigated. By substituting Gd with Y, the area fraction of bulk-shaped long-period stacking ordered phases (LPSO) increases, while one of eutectic Mg2Ni phase decreases slightly. Moreover, it also promotes the precipitations of lamellar LPSO phase and nanoscale stacking faults (SFs). The tensile tests showed that the addition of Y increased the yield strength by about 40 MPa, mainly due to the strengthening of the kink deformation of the bulk shaped LPSO phase, the hindering effect of the lamellar LPSO and SF on dislocation movement, and the strengthening caused by grain refinement. As a result, the Mg-5Gd-3Y–5Ni (MGYN) alloy exhibits excellent mechanical properties with tensile yield strength (TYS) of 288 MPa, ultimate tensile strength (UTS) of 364 MPa, and elongation (EL) of 8.3 %. Moreover, although the fraction of Mg2Ni phase with high electrochemical potential is decreased, the reduction in dissolution rate is not significant because the discontinuous distribution of lamellar LPSO in the grains intensifies the galvanic corrosion by increasing the proportion of cathode phase. As a result, the coexistence of Mg2Ni and LPSO phases can observably improve the dissolution rate. Finally, the highest dissolution rate (234.56 mg cm−2 h−1 in 3 wt% KCl solution at 93 °C) reported so far for the dissoluble magnesium alloys can be attained for MGYN alloy in this study. This work provides an economical material selection with high dissolution rate and sufficient strength for the fabrication of the fracturing plugging tools.

Keywords

• Mg-Gd-(Y)–Ni alloys
• LPSO phase
• Mechanical properties
• Dissolution behaviors
• Stacking faults