Preparation, Characterization and Electrochemical Response of Nanostructured TiAlV with Potentiostatically Deposited IrOx as a pH Sensor for Rapid Detection of Inflammation
Jitřenka Jírů,
Vojtěch Hybášek,
Alena Michalcová,
Klára Korbelová,
Lukáš Koláčný,
Jaroslav Fojt
Affiliations
Jitřenka Jírů
Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Vojtěch Hybášek
Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Alena Michalcová
Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Klára Korbelová
Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Lukáš Koláčný
Department of Organic Technology, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Jaroslav Fojt
Department of Metals and Corrosion Engineering, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague, Czech Republic
Electrochemical pH sensors have a wide range of industrial applications such as in medicine due to their fast response and high sensitivity to pH changes. This work focuses on the preparation of samples based on the nanostructure of TiO2 with potentiostatically deposited particles of iridium and its oxides (IrO2), using a Ti-6Al-4V alloy as the base material, and subsequent surface characterization. Transmission electron microscopy and secondary ion mass spectroscopy showed Ir particles distributed in the nanotubes. Using a potentiostatic method, a stable pH sensor was prepared. By monitoring the open circuit potential, it was shown that this sensor is usable even without being kept in a storage medium and does not react to changes in the redox potential of the solution.
