Additive Manufacturing Letters (Dec 2022)
Enhanced strength and ductility of laser powder bed fused NbMoTaW refractory high-entropy alloy via carbon microalloying
Abstract
NbMoTaW refractory high-entropy alloy (RHEA) shows outstanding mechanical properties at ultra-high temperatures, while room-temperature brittleness limits its application. In this study, carbon (C) microalloying was employed to improve the room-temperature brittleness resistance of NbMoTaW RHEA fabricated using laser powder bed fusion (LPBF). The addition of 0.5-at% C leads to good formability and remarkable microalloying effects. Nano-NbC precipitates distributed at grain boundaries and dislocations effectively refined the grain size. The yield strength, ultimate compression strength, and ductility were successfully improved up to 1725 MPa, 1782 MPa, and 7.0%, respectively. Nano-NbC carbide precipitates in the form of diffusion transformation during multiple reheating was verified by thermodynamics, kinetics calculations, and microstructure characterization. C microalloying endowed NbMoTaW RHEA with remarkable enhancements of strength and ductility, which suggested a strategy for designing strong and ductile RHEA through LPBF.