Design of a plasmonic back reflector using Ag nanoparticles with a mirror support for an a-Si:H solar cell

Abstract

Plasmonic nanoparticles have unique optical properties and these properties are affected by any surrounding structures, or lack thereof. Nanoparticles are often added to a device without fully assessing the effect that each interface will have on the nanoparticle’s response. In this work, we simulate and fabricate devices utilizing hemispherical nanoparticles integrated into the back reflector of an amorphous silicon solar cell. 3D finite difference time domain simulations were used to calculate the optical absorption of a 300nm amorphous silicon layer as a function of the size of the nanoparticles, the distance between the nanoparticles and the active layer, and the distance between the nanoparticles and the mirror. Two transparent conducting oxides, aluminum doped zinc oxide and indium tin oxide, are investigated to determine the importance of the material properties between the nanoparticles and mirror. Silver hemispherical nanoparticles with a diameter of 150nm placed directly on the a-Si:H and a 60nm aluminum doped zinc oxide layer between the nanoparticles and the mirror lead to a maximum absorption increase of 7.2% in the 500nm to 800nm wavelength range. Experimental devices confirmed the trends predicted by theory but did not achieve enhancement, likely due to fabrication challenges. Fabricating a solar cell with the simulated design requires a high quality transparent conductive oxide and high control over the nanoparticle size distribution.