9-[4-(Azidomethyl)phenyl]-9H-carbazole-3-carbonitrile

C. Ramathilagam; P. R. Umarani; N. Venkatesan; P. Rajakumar; B. Gunasekaran; V. Manivannan

doi:10.1107/S1600536814001391

Acta Crystallographica Section E (Feb 2014)

9-[4-(Azidomethyl)phenyl]-9H-carbazole-3-carbonitrile

C. Ramathilagam,
P. R. Umarani,
N. Venkatesan,
P. Rajakumar,
B. Gunasekaran,
V. Manivannan

Affiliations

C. Ramathilagam: Department of Physics, AMET University, Kanathur, Chennai 603 112, India
P. R. Umarani: Principal, Kundavai Nachiyar Govt College for Women, Thanjavur 613 007, India
N. Venkatesan: Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India
P. Rajakumar: Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India
B. Gunasekaran: Department of Physics & Nano Technology, SRM University, SRM Nagar, Kattankulathur, Kancheepuram Dist., Chennai 603 203, Tamil Nadu, India
V. Manivannan: Department of Research and Development, PRIST University, Vallam, Thanjavur 613 403, Tamil Nadu, India

DOI: https://doi.org/10.1107/S1600536814001391
Journal volume & issue: Vol. 70, no. 2
pp. o197 – o197

Abstract

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In the title compound C20H13N5, the dihedral angle between the carbazole ring system (r.m.s. deviation = 0.027 Å) and the pendant benzene ring is 55.08 (6)°. One of the azide N atoms is disordered over two positions in a 0.65 (2):0.35 (2) ratio. In the crystal, aromatic π–π stacking is observed [minimum centroid–centroid separation = 3.6499 (13) Å] as well as inversion-dimers connected by pairs of weak C—H...π interactions.

Published in Acta Crystallographica Section E

ISSN: 1600-5368 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://journals.iucr.org/e/

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