Acta Crystallographica Section E (Aug 2011)

Methyl 4-[(5-chloropyrimidin-2-yl)carbamoyl]benzoate

  • Chun-Hsiang Lu,
  • Chia-Jun Wu,
  • Chun-Wei Yeh,
  • Jhy-Der Chen

DOI
https://doi.org/10.1107/S1600536811025268
Journal volume & issue
Vol. 67, no. 8
pp. o1872 – o1872

Abstract

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Molecules of the title compound, C13H10ClN3O3, form centrosymmetric dimers via intermolecular N—H...N hydrogen bonds generating an R22(8) motif. The dimers are further connected through an O...Cl—C halogen bond [O...Cl = 3.233 (1) Å and O...Cl—C = 167.33 (1)°] into a chain along [110]. The secondary amide group adopts a cis conformation. Weak C—H...N hydrogen bonds among the methyl benzoate and pyrimidyl rings are also observed in the crystal structure.