Acta Crystallographica Section E (Dec 2011)

Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]cobalt(II)

  • Hai-Rong Wang,
  • Guo-Ting Li

DOI
https://doi.org/10.1107/S1600536811046496
Journal volume & issue
Vol. 67, no. 12
pp. m1743 – m1743

Abstract

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In the title compound, [Co(C12H8NO2)2(H2O)4], the Co atom lies on a twofold rotation axis and has an N2O4 octahedral coordination environment formed by four O atoms of water molecules in the equatorial plane and two apical N atoms of pyridine groups. An intricate three-dimensional supramolecular network is formed by multiple O—H...O hydrogen bonds between the coordinated water molecules and the uncoordinated carboxylate groups.