Formation and stability of studtite in bicarbonate-containing waters

Abstract

Studtite and meta-studtite are the only two uranyl peroxides found in nature. Sparsely soluble studtite has been found in natural uranium deposits, on the surface of spent nuclear fuel in contact with water and on core material from major nuclear accidents such as Chernobyl. The formation of studtite on the surface of nuclear fuel can have an impact on the release of radionuclides to the biosphere. In this work, we have experimentally studied the formation of studtite as function of HCO3- concentration and pH. The results show that studtite can form at pH ≤ 10 in solutions without added HCO3-. At pH ≤ 7, the precipitate was found to be mainly studtite, while at 8 ≤ pH ≤ 9.8, a mixture of studtite and meta-schoepite was found. Studtite formation from UO22+ and H2O2 was observed at [HCO3-] ≤ 2 mM and studtite was only found to dissolve at [HCO3-] > 2 mM.

Keywords

• Studtite
• XRD
• PH
• γ-radiation
• Geological repository