Acta Crystallographica Section E (Aug 2012)

Bis[2-(2-hydroxymethyl)pyridine-κ2N,O](pivalato-κO)copper(II)

  • M. Mobin Shaikh,
  • Veenu Mishra,
  • Priti Ram,
  • Anil Birla

DOI
https://doi.org/10.1107/S1600536812030917
Journal volume & issue
Vol. 68, no. 8
pp. m1055 – m1055

Abstract

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The structure of the centrosymmetric title complex, [Cu(C5H9O2)2(C6H7NO)2], has the CuII atom on a centre of inversion. The CuII atom is six-coordinate with a distorted octahedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxylate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by intermolecular C—H...O and intramolecular O—H...O hydrogen-bond interactions.