Synergistic bromothymol blue dye degradation with hydrodynamic cavitation and hydrogen peroxide (HC-H2O2)

Abstract

This study assessed the degradation of bromothymol blue in a Venturi device based on a hybrid process that combines hydrodynamic cavitation (HC) and hydrogen peroxide (H2O2). A Rotatable Central Composite Design (RCCD) was used to optimize the following variables: pressure, reaction time and molar ratio of hydrogen peroxide. Degradation efficiencies were evaluated based on Chemical Oxygen Demand (COD) and color removals before and after Venturi treatment. Maximum COD (93.42%) and color (93.28%) removals were observed at 4.0 bar inlet pressure, at a treatment time of 25 minutes and at H2O2/effluent (dye) molar ratio of 30:1. The hydrodynamic cavitation/hydrogen peroxide system has great potential to remove normally recalcitrant organic pollutants.

Keywords

• advanced oxidation process
• rotatable central composite design
• venturi