Energies (Nov 2021)

Efficient n-i-p Monolithic Perovskite/Silicon Tandem Solar Cells with Tin Oxide via a Chemical Bath Deposition Method

  • Jiyeon Hyun,
  • Kyung Mun Yeom,
  • Ha Eun Lee,
  • Donghwan Kim,
  • Hae-Seok Lee,
  • Jun Hong Noh,
  • Yoonmook Kang

DOI
https://doi.org/10.3390/en14227614
Journal volume & issue
Vol. 14, no. 22
p. 7614

Abstract

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Tandem solar cells, based on perovskite and crystalline silicon absorbers, are promising candidates for commercial applications. Tin oxide (SnO2), applied via the spin-coating method, has been among the most used electron transfer layers in normal (n-i-p) perovskite/silicon tandem cells. SnO2 synthesized by chemical bath deposition (CBD) has not yet been applied in tandem devices. This method shows improved efficiency in perovskite single cells and allows for deposition over a larger area. Our study is the first to apply low-temperature processed SnO2 via CBD to a homojunction silicon solar cell without additional deposition of a recombination layer. By controlling the reaction time, a tandem efficiency of 16.9% was achieved. This study shows that tandem implementation is possible through the CBD method, and demonstrates the potential of this method in commercial application to textured silicon surfaces with large areas.

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