Tuning the selectivity of catalytic nitriles hydrogenation by structure regulation in atomically dispersed Pd catalysts

Zhibo Liu; Fei Huang; Mi Peng; Yunlei Chen; Xiangbin Cai; Linlin Wang; Zenan Hu; Xiaodong Wen; Ning Wang; Dequan Xiao; Hong Jiang; Hongbin Sun; Hongyang Liu; Ding Ma

doi:10.1038/s41467-021-26542-y

Nature Communications (Oct 2021)

Tuning the selectivity of catalytic nitriles hydrogenation by structure regulation in atomically dispersed Pd catalysts

Zhibo Liu,
Fei Huang,
Mi Peng,
Yunlei Chen,
Xiangbin Cai,
Linlin Wang,
Zenan Hu,
Xiaodong Wen,
Ning Wang,
Dequan Xiao,
Hong Jiang,
Hongbin Sun,
Hongyang Liu,
Ding Ma

Affiliations

Zhibo Liu: Department of Chemistry, Northeastern University
Fei Huang: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Mi Peng: Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, and BIC-ESAT, Peking University
Yunlei Chen: State Key Laboratory of Coal Conversion, Institute Coal Chemistry, Chinese Academy of Sciences
Xiangbin Cai: Department of Physics and Center for Quantum Materials, Hong Kong University of Science and Technology
Linlin Wang: Department of Chemistry, Northeastern University
Zenan Hu: Department of Chemistry, Northeastern University
Xiaodong Wen: State Key Laboratory of Coal Conversion, Institute Coal Chemistry, Chinese Academy of Sciences
Ning Wang: Department of Physics and Center for Quantum Materials, Hong Kong University of Science and Technology
Dequan Xiao: Center for Integrative Materials Discovery, Department of Chemistry and Chemical Engineering, University of New Haven
Hong Jiang: Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, and BIC-ESAT, Peking University
Hongbin Sun: Department of Chemistry, Northeastern University
Hongyang Liu: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Ding Ma: Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, and BIC-ESAT, Peking University

DOI: https://doi.org/10.1038/s41467-021-26542-y
Journal volume & issue: Vol. 12, no. 1
pp. 1 – 8

Abstract

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The selective hydrogenation of nitriles to prepare corresponding amines is highly desired in chemistry industry. Here, the authors selectively obtained secondary amines and primary amines over two types of atomically dispersed Pd catalysts supported on the nanodiamond-graphene hybrid support.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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