Novel three-dimensional coordination polymer of 2-(1,3,5-triaza-7-phosphoniatricyclo[3.3.1.13,7]decan-7-yl)ethanoic acid with silver(I) tetrafluoroborate

Abstract

An AgI-based coordination polymer (CP), namely, poly[[[μ3-2-(1,3,5-triaza-7-phosphoniatricyclo[3.3.1.13,7]decan-7-yl)ethanoate-κ4N:N′:O,O′]silver(I)] tetrafluoroborate], {[Ag(C9H16N3O2P)]BF4}n, was synthesized in an aqueous solution of zwitterionic 2-(1,3,5-triaza-7-phosphoniatricyclo[3.3.1.13,7]decan-7-yl)ethanoate (L) and AgBF4 with exclusion of light at room temperature. The colourless and light-insensitive CP crystallized in the monoclinic space group Cc. The asymmetric unit consists of an AgI cation, the zwitterionic L ligand and a BF4− counter-ion. Each AgI ion is coordinated by two carboxylate oxygen atoms in a chelating coordination mode, as well as one of the nitrogen atoms of two neighbouring L ligands. The crystal structure of the CP was classified as a unique three-dimensional arrangement. The CP was also characterized in aqueous solutions by multinuclear NMR and HRMS spectroscopies and elemental analysis.

Keywords

• crystal structure
• coordination polymer
• silver
• phosphabetaine
• tetrafluoroborate