Application of NO Reduction Dynamical Model in SNCR Denitration System Based on Biomass

Abstract

In recent years, studies on denitration by applying biomass reburning method has drawn the attention of many researchers due to the characteristics of low sulfur and nitrogen content, high volatile, high ash focal activity, zero CO2 net emissions, etc. Based on Chemkin software and selective non-catalytic reduction (SNCR) denitration chemical kinetic model, this paper conducted SNCR denitration chemical kinetic modeling. And the results showed that: with the increase of residence time, under the different initial concentration of NO, SNCR denitration efficiency tends to stabilize after the first increase. Moreover, the higher the initial concentration of NO, the longer the residence time which is required to achieve the greatest denitration efficiency. With the increase of ammonia nitrogen ratio, SNCR denitration efficiency increases step by step. When the normalized stoichiometric ratio (NSR) is greater than 1.5, the denitration efficiency is at a basic stable state. Under the same conditions, simulation results of the SNCR results agree well with the test results. Therefore, it can be concluded that carrying out the SNCR denitration chemical dynamics simulation using Chemkin software can provide a reference for tests and mechanism researches on SNCR, biomass reburning and advanced reburning denitration.

Keywords

• Biomass
• NO
• Selective non-catalytic reduction
• Denitration
• Additional agent
• Reduction kinetics